Near-infrared electrochemiluminescence from orange fluorescent Au nanoclusters in water

We report the unusual generation of near-infrared (near-IR) electrochemiluminescence (ECL) from water-soluble gold nanoclusters (Au NCs). Although their photoluminescence is mainly in the visible wavelength region, the near-IR ECL is attributed to the Au(0)–glutathione motif in the Au NCs stabilized by glutathione in water.

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